伏安法教程 第2版（英文版） rb mobi 在线 下载 lit txt 网盘 pdf

　　伏安法是基本的测量电阻的手段，也是电分析化学中基本及简单的检测手段之一，在科学研究和生产实践中有广泛的应用。本书作为一本教材，详细地介绍了各种伏安法实验的设计和应用，并对伏安法中可能遇到的难点给出了严谨的解决方案。本书版系畅销教材，第二版在版的基础上增加了两章，以便读者更好的学习、理解。这套教材和习题，原版十分畅销，中科院长春应化所的彭章泉博士曾写信给作者，觉得此书非常好，拜读了10遍以上。中科院的万立俊研究员认为此书非常好，是物理化学领域的高端图书。

目次：电化平衡和Nernst方程；电极动力学；扩散；大电极上的循环伏安法；显微电极上的伏安法；非均匀曲面上的伏安法；循环伏安法：耦合均相动力学和吸附；流体动力电极；影响因子伏安法；弱支持介质中的伏安法；纳米度量中的伏安法。附：电极过程模拟。

读者对象：物理化学相关专业的研究生、教师和相关的科研人员。

Preface

1 Equilibrium Electrochemistry and the Nernst Equation

1.1 Chemical Equilibrium

1.2 Electrochemical Equilibrium: Introduction

1.3 Electrochemical Equilibrium: Electron Transfer at the Solution-Electrode Interface

1.4 Electrochemical Equilibrium: The Nernst Equation

1.5 Walther Hermann Nernst

1.6 Reference Electrodes and the Measurement of Electrode Potentials

1.7 The Hydrogen Electrode as a Reference Electrode

1.8 Standard Electrode Potentials and Formal Potentials

1.9 Formal Potentials and Experimental Voltammetry

1.10 Electrode Processes: Kinetics vs. Thermodynamics

2 Electrode Kinetics

2.1 Currents and Reaction Fluxes

2.2 Studying Electrode Kinetics Requires Three Electrodes

2.3 Butler-Volmer Kinetics

2.4 Standard Electrochemical Rate Constants and Formal Potentials

2.5 The Need for Supporting Electrolyte

2.6 The Tafel Law

2.7 Julius Tafel

2.8 Multistep Electron Transfer Processes

2.9 Tafel Analysis and the Hydrogen Evolution Reaction

2.10 B. Stanley Pons

2.11 Cold Fusion -- The Musical!

2.12 Why Are Some Standard Electrochemical Rate Constants Large but Others Slow? The Marcus Theory of Electron Transfer: An Introduction

2.13 Marcus Theory: Taking it Further. Inner and Outer Sphere Electron Transfer

2.14 Marcus Theory: Taking it Further. Adiabatic and Non-Adiabatic Reactions

2.15 Marcus Theory: Taking it Further. Calculating the Gibbs Energy of Activation

2.16 Relationship between Marcus Theory and Butler-Volmer Kinetics

2.17 Marcus Theory and Experiment. Success!

3 Diffusion

3.1 Fick's 1st Law of Diffusion

3.2 Fick's 2nd Law of Diffusion

3.3 The Molecular Basis of Fick's Laws

3.4 How Did Fick Discover His Laws?

3.5 The Cottrell Equation: Solving Fick's 2nd Law

3.6 The Cottrell Problem: The Case of Unequal Diffusion Coefficients

3.7 The Nernst Diffusion Layer

3.8 Mass Transfer vs. Electrode Kinetics: Steady-State Current-Voltage Waveshapes

3.9 Mass Transport Corrected Tafel Relationships

4 Cyclic Voltammetry at Macroelectrodes

4.1 Cyclic Voltammetry: The Experiment

4.2 Cyclic Voltammetry: Solving the Transport Equations

4.3 Cyclic Voltammetry: Reversible and Irreversible Kinetics

4.4 What Dictates'Reversible' and'Irreversible' Behaviour?

4.5 Reversible and Irreversible Behaviour: The Effect of Voltage Scan Rate

4.6 Reversible versus Irreversible Voltammetry: A Summary

4.7 The Measurement of Cyclic Voltammograms: Three Practical Considerations

……

5 Voltammetry at Microelectrodes

6 Voltammetry at Heterogeneous Surfaces

7 Cyclic Voltammetry: Coupled Homogeneous Kinetics and Adsorption

8 Hydrodynamic Electrodes

9 Voltammetry for Electroanalysis

10 Voltammetry in Weakly Supported Media: Migration and Other Effects

11 Voltammetry at the Nanoscale

Appendix: Simulation of Electrode Processes

Index

　　Richard G. Compton（R.G.卡普顿,英国)是国际知名学者，在数学和物理学界享有盛誉。本书凝聚了作者多年科研和教学成果，适用于科研工作者、高校教师和研究生。

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